Journal of Applied Sciences ›› 1996, Vol. 14 ›› Issue (4): 457-462.

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HIGH PRESSURE EFFECTS ON THE DIFFUSED PHASE TRANSITION OF Pb (Fe1/2Nb1/2)O3-Pb(Fe2/3W1/3)O3 CERAMIC

ZHANG YIBING1, WANG BO1, JIN BIANJUN1, CHENG DAREN2   

  1. 1. Shanghai University, Jiading Oampus;
    2. Shanghai Institute of Oeramic, Academia Sinica
  • Received:1995-05-12 Revised:1995-07-14 Online:1996-12-31 Published:1996-12-31

Abstract: The dielectric constant ε of Pb(Fe1/2Nb1/2)O3-Ph(Fe2/3W1/3)O3 binary system has been measured at high hydrostatic pressures from 0 to 14kbar and temperature from -190℃ to 100℃. The experimental results indicate that temperature and pressure-induced phase transitions are diffused. With increasing pressure, the phase transition temperature Tm drops linearly with dTm/dP=-3.1℃/kbar, maximum permittivity εmax decreases, and the diffusion degree of the phase transition increases. These properties of diffused phase transition at high pressure are discussed phenomenologically in this paper.

Key words: high pressure, ferroelectrics, diffused phase transition