Journal of Applied Sciences ›› 1992, Vol. 10 ›› Issue (1): 85-94.

• Articles • Previous Articles    

CATALYST PRERATION OF POLYMER BOUND RUTHENIUM (Ⅲ) COMPLEXES CONTAINING BINUCLEAR LIGANDS AND ACTIVITY OF CATALYTIC HYDROGENATION

ZHAO WEIJUN, WANG LING, ZHANG SHUJI, FANG YANQUAN   

  1. Naikai University
  • Received:1989-12-30 Revised:1991-03-18 Online:1992-03-31 Published:1992-03-31

Abstract: With Chloromethylated polystyrene divinylbenzene as a support, the funotionalizened polymers containing N-P, N-0, or N-N binuelear ligand were pi-epared. These functionalized polymers were chemically bound with RuCl3 forming supported catalysts. Used in the hydrogenation of Diketo-alcohol the catalysts displayed high activity and selectivity.

Key words: complex catalyst, supported catalyst, hydrogenation reaction, ruthenium, binuolear liganda