自由基照相中光显影研究

应用科学学报 ›› 1985, Vol. 3 ›› Issue (3): 255-261.

自由基照相中光显影研究

郑广霖, 石道钧, 黄晓兰

中国科学院化学研究所

收稿日期:1982-04-13 修回日期:1983-06-26 出版日期:1985-09-30 发布日期:1985-09-30

STUDIES IN OPTICAL DEVELOPMENT OF FREE RADICAL PHOTOGRAPHY

ZHENG GUANGLIN, SHI DAOJUN, HUANG XIAOLAN

Institute of Chemistry Academia Sinica

Received:1982-04-13 Revised:1983-06-26 Online:1985-09-30 Published:1985-09-30

摘要/Abstract

摘要： 本文研究了由无色结晶紫(LCV)和CBr₄组成的自由基光敏片的红光显影特性.提出用图像强化系数K_max作为光显影效果定量表征参数,研究了光波长对光显影效果的影响,并对光显影中的诱导期作了解释,认为主要是氧的存在引起的.

Abstract: A quantitative characterization parameter in. optical development of free radical photography K_max is proposed and its significance and method of measurement are elucidated. Effects of the wavelength (used) on the optical development of Leuco crystal violet/CBr₄ film and the effects of the adhesive medium and temperature on the rate of optical development have been studied. The activation energy is estimated at about 10kcal/mole.
The induction period of optical development has also been interpreted. There are two different processes in optical development. In the induction period oxygen quenching of the excited dye molecules by the diffusion-control predominates while in the main period of the reaction energy transfer-control photochemical reaction predominates.

郑广霖, 石道钧, 黄晓兰. 自由基照相中光显影研究[J]. 应用科学学报, 1985, 3(3): 255-261.

ZHENG GUANGLIN, SHI DAOJUN, HUANG XIAOLAN. STUDIES IN OPTICAL DEVELOPMENT OF FREE RADICAL PHOTOGRAPHY[J]. Journal of Applied Sciences, 1985, 3(3): 255-261.