应用科学学报 ›› 1986, Vol. 4 ›› Issue (2): 175-181.

• 论文 • 上一篇    下一篇

固体粒子对浓悬浮液流变性能的影响

朱万章   

  1. 北工部海洋涂料研究所
  • 收稿日期:1983-09-23 修回日期:1984-12-22 出版日期:1986-06-30 发布日期:1986-06-30

EFFECT OF SOLID PARTICLES ON RHEOLOGICAL PROPERTIES IN CONCENTRATED SUSPENSIONS

ZHU WANZHANG   

  1. Marine Coatings Research Institute
  • Received:1983-09-23 Revised:1984-12-22 Online:1986-06-30 Published:1986-06-30

摘要: 以高氯酸铵和铝粉为分散相,端羟聚醚二醇为连续相,考察了总固体粒子的体积分数φ,粒度比R,以及小粒子占固体总量的体积分数φs对浓悬浮液流变性能的影响.对双峰分布分散系,浓悬浮液的粘度在φs=0.30时达到最小,并随R的减小而下降.固体细粒子对浓悬浮液的假塑性程度关系极大.当悬浮液中细粒固体增加或粒度比减小时,体系假塑性程度增大;有非球形粒子的悬浮液中,φφs的影响更大,但宽分布球形粒子构成的二元系,φ对假塑性的影响比窄分布体系小.

Abstract: The effects of the volume fraction of solid particles, φ, the ratio of particle diameters, R, and the volume fraction of small particles in solid amount, φs, on rheological properties in concentrated suspensions were studied. Commercial ammonium perchlorate and aluminium powder were used as dispersed phase, and a polyether diol as continuous phase. In bimodal dispersed systems the viscosity of the systems is minimum at φs=0.30, and decreases as R decreases. The influence of small particles is shown to be very important in the pseudoplastic behavior of concentrated suspensions. With the increase of small particle content or the decrease of particle diameter ratio in suspension, the pseudoplastio extent of the system increases. The effects of φ and φs on system become stronger when non-spherical particles exist in suspension. In bimodal system with wide distribution of spherical particle size the effect of φ on the pseudoplasticity of the system is less than that in the system with narrow distribution.