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应用科学学报 ›› 1987, Vol. 5 ›› Issue (2): 131-137.

• 论文 • 上一篇    下一篇

有效结构理论应用于苯+环己烷+四氯化碳三元体系

严文兴, 孙亚平   

  1. 浙江大学
  • 收稿日期:1984-11-09 修回日期:1986-07-23 出版日期:1987-06-30 发布日期:1987-06-30

APPLICATION OF SIGNIFICANT STRUCTURE THEORY TO THE STUDY OF THE TERNARY SYSTEM:BENZENE-CYCLOHEXANE-CARBON TETRACHLORIDE

YEN WENHSING, SUN YAPING   

  1. Zhejiang University
  • Received:1984-11-09 Revised:1986-07-23 Online:1987-06-30 Published:1987-06-30

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摘要： 本文概述了Eyring的有效结构理论对液体二元体系的应用,并简化了计算方法.在此基础上,根据已知苯+环己烷,苯+四氯化碳和环己烷+四氯化碳三个二元体系的二元参数,将有效结构理论用于预测苯+环己烷+四氯化碳三元体系的过量函数值.结果与HE的实验值,VE在别的温度下的实验值和GE的其他方法计算值相比较,符合良好.

Abstract: By its successful application to the study of binary system, the significant, structure theory was advanced to the study of the ternary system, benzene-cyclohexane-oarbon tetraohloride, in the evaluation of excess volumes, excess enthalpies and excess Gibbs free energies. The result agrees well with the published and calculated data.