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应用科学学报 ›› 1992, Vol. 10 ›› Issue (1): 85-94.

• 论文 • 上一篇    

高聚物含双核配体键联钌络合物催化剂的制备及其催化加氢活性

赵维君, 王玲, 张书笈, 方延铨   

  1. 南开大学
  • 收稿日期:1989-12-30 修回日期:1991-03-18 出版日期:1992-03-31 发布日期:1992-03-31

CATALYST PRERATION OF POLYMER BOUND RUTHENIUM (Ⅲ) COMPLEXES CONTAINING BINUCLEAR LIGANDS AND ACTIVITY OF CATALYTIC HYDROGENATION

ZHAO WEIJUN, WANG LING, ZHANG SHUJI, FANG YANQUAN   

  1. Naikai University
  • Received:1989-12-30 Revised:1991-03-18 Online:1992-03-31 Published:1992-03-31

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摘要： 以氯甲基化聚苯乙烯-二乙烯基苯树脂为载体,分别制得含氮-磷、氮-氮、氮-氧双核配体的功能高分子,这些功能高分子化学键联三氯化钌获得固载化催化剂,应用于二丙酮醇加氢反应,具有较高的活性和选择性.

关键词: 络合催化剂, 钌, 固载化催化剂, 加氢反应, 双核配体

Abstract: With Chloromethylated polystyrene divinylbenzene as a support, the funotionalizened polymers containing N-P, N-0, or N-N binuelear ligand were pi-epared. These functionalized polymers were chemically bound with RuCl3 forming supported catalysts. Used in the hydrogenation of Diketo-alcohol the catalysts displayed high activity and selectivity.

Key words: complex catalyst, supported catalyst, hydrogenation reaction, ruthenium, binuolear liganda