微波技术在制备水滑石和柱撑水滑石中的应用

应用科学学报 ›› 1998, Vol. 16 ›› Issue (3): 349-354.

微波技术在制备水滑石和柱撑水滑石中的应用

杜以波¹, 何静¹, 李峰¹, D G Evans², 段雪¹, 王作新¹

1. 北京化工大学;
2. 英国Exeter大学

收稿日期:1997-04-07 修回日期:1997-07-18 出版日期:1998-09-30 发布日期:1998-09-30
作者简介:杜以波:硕士,北京化工大学应用化学系,北京 100029
基金资助:
国家自然科学基金

Preparation of Hydrotalcite and Hydrotalcite-Like Compounds by Microwave Techniques

DU YIBO¹, HE JING¹, LI FENG¹, DAVID G. EVANS², DUAN XUE¹, WANG ZUOXIN¹

1. Department of Applied Chemistry, Beijing University of Chemical Technology, Beijing 100029;
2. Exeter University, England

Received:1997-04-07 Revised:1997-07-18 Online:1998-09-30 Published:1998-09-30

摘要/Abstract

摘要： 在制备水滑石的过程中使用了微波技术进行晶化,并与常规晶化方法进行了对比.XRD结果表明微波晶化法可以在约8分钟内达到常规热晶化法24小时一样的效果.在制备1,5-萘二磺酸柱撑水滑石的过程中,使用了微波技术进行离子交换插入.XRD结果表明,微波作用10分钟与常规热交换法72小时具有一样甚至更好的离子交换效果.用微波插入法制备了磷钨酸柱撑水滑石,XRD和TPDE结果表明磷钨酸分子与水滑石层板离子之间形成了强烈的相互作用.

关键词: 水滑石, 柱撑水滑石, 微波技术

Abstract: Hydrotalcite Mg₆ Al₂(OH) ₁₆ CO₃·4H₂O has been prepared by using both microwave irradiation and conventional heating methods during the ageing process. X-ray diffraction show s that the same materials are obtained in each case, but the microwave process is superior in that a much shorter aging time is required. Mg₄ Al₂(OH) ₁₂[C₁₀ H₆(SO₃) ₂]·4H₂O has been prepared by using microwave and conventional heating methods during the intercalation process. XRD indicates that the sample produced by the microwave method is superior to that produced by conventional heating. Mg₄Al₂(OH) ₁₂(PW₁₂O₄₀) ^2/3·4H₂O has been prepared by microwave methods. XRD and TPDE show that there is a strong interaction between the heteropolyanion and the layers of hydrotalcite.

Key words: microwave techniques, hydrotalcite, hydrotalcite-like compounds

杜以波, 何静, 李峰, D G Evans, 段雪, 王作新. 微波技术在制备水滑石和柱撑水滑石中的应用[J]. 应用科学学报, 1998, 16(3): 349-354.

DU YIBO, HE JING, LI FENG, DAVID G. EVANS, DUAN XUE, WANG ZUOXIN. Preparation of Hydrotalcite and Hydrotalcite-Like Compounds by Microwave Techniques[J]. Journal of Applied Sciences, 1998, 16(3): 349-354.