邻甲苯胺的电化学合成及其阴极反应机理的研究

应用科学学报 ›› 1990, Vol. 8 ›› Issue (4): 326-332.

邻甲苯胺的电化学合成及其阴极反应机理的研究

桂伟志

南开大学

收稿日期:1989-02-26 修回日期:1989-07-04 出版日期:1990-12-31 发布日期:1990-12-31

ELECTROCHEMICAL SYNTHESIS OF ORTHO AMINO TOLUENE AND A STUDY OF ITS CATHODIC REACTION MECHANISM

GUI WEIZHI

Nankai University

Received:1989-02-26 Revised:1989-07-04 Online:1990-12-31 Published:1990-12-31

摘要/Abstract

摘要： 介绍邻甲苯胺的电化学合成新方法及其阴极反应机理的研究.为了找出最佳电解电位范围,在电解进行之前,均需先测出每种溶液体系的极化曲线.其产品收率为80%,电流效率为98%.作者经反复试验已推测其阴极反应机理为EEC三个分步,并指出电合成效果与电极反应机理间的关系.

Abstract: In this paper a new process for the electrochemical synthesis of ortho amino toluene and a study of its cathodic reaction mechanism are introduced. For the sake of seeking out an optimum electrolytic potential, polarization curves of the solutions must be determined before electrolysis. Its product yield andcurrent efficiency are 80% and 98% respectively.
From repeated trials, the author has deduced that its cathodic reaction mechanism is a three-step EEC, and has pointed out the relations between electro-synthesis and its electrode reaction mechanism.

桂伟志. 邻甲苯胺的电化学合成及其阴极反应机理的研究[J]. 应用科学学报, 1990, 8(4): 326-332.

GUI WEIZHI. ELECTROCHEMICAL SYNTHESIS OF ORTHO AMINO TOLUENE AND A STUDY OF ITS CATHODIC REACTION MECHANISM[J]. Journal of Applied Sciences, 1990, 8(4): 326-332.