English

应用科学学报 ›› 1998, Vol. 16 ›› Issue (2): 191-199.

• 论文 • 上一篇    下一篇

气体吸附理论的研究

杨庆贤1, 卢学栋2   

  1. 1. 福建林学院;
    2. 中国科学院山西煤炭化学研究所
  • 收稿日期:1996-09-07 修回日期:1996-12-19 出版日期:1998-06-30 发布日期:1998-06-30
  • 作者简介:杨庆贤:教授,福建林学院基础科学系,福建南平 353001
  • 基金资助:
    福建省自然科学基金

A Study on Adsorptive Theory of Real Gases

YANG QINGXIAN1, LU XUEDONG2   

  1. 1. Fujian Forestry college, nanping 353001;
    2. Institute of the coal Chemistry of Shan Xi, Chinese Academy of Science, Taiyuan 030001
  • Received:1996-09-07 Revised:1996-12-19 Online:1998-06-30 Published:1998-06-30

PDF

148

被引次数

27

摘要： 应用统计力学研究实际气体吸附,导出了吸附方程式的普遍形式,并给出气体分子在Keesom势和L-J势作用下的具体形式.应用自动吸附仪测定微孔和中孔活性炭吸附N2的实验等温线,微孔炭的实验等温线和理论等温线吻合程度令人满意.

关键词: 多分子层吸附, 实际气体, 等温方程式, 统计力学

Abstract: In this paper, the adsorption is studied in the light of statistical mechanics, with the result that a universal isotherm equation of the adsorption has been found, and the practical isotherm equation for real gases is given when the interaction between gas molecules is depicted in terms of Keesom and the Lennard-Jones potential. The experimental isotherms of the adsorption of medium and micro aperture charcoal are measured. It is seen that the agreement between theoretical and experimental isotherms of micro aperture charcoal is satisfred.

Key words: multimolecular adsorption, statistical mechanics, real gas, isotherm equation