Journal of Applied Sciences ›› 1988, Vol. 6 ›› Issue (2): 169-174.

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THEORY OF PHASE TRANSITION IN THE LAYERED ANTIFERRO-ELECTRIC H2C4O4

ZHANG JINGBO1, SUN HEBI2, QIN ZIKAI1   

  1. 1. Shandong University;
    2. Shanghai Jiao Tong University
  • Received:1985-07-08 Revised:1985-12-30 Online:1988-06-30 Published:1988-06-30

Abstract: The para-and antiferro-electric phase transition of an H2C4O4 crystal is studied by means of Green's function theory based upon a pseudospin model and by taking into account its layered structure. We derive a first order transition instead of a second order one as concluded by Zinenko with the same model. We also find the change of the order parameter with temperature in better conformity with measurements.