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应用科学学报 ›› 1984, Vol. 2 ›› Issue (3): 274-276.

• 论文 • 上一篇    下一篇

二氟一氯甲烷的激光裂解

穆国融, 李长林   

  1. 复旦大学
  • 收稿日期:1982-04-12 出版日期:1984-09-30 发布日期:1984-09-30

THE MECHANISM OF PHOTOLYSIS OF CF2HCL BY CO2 LASER

MUO GUORONG, LI CHANGLIN   

  1. Laser Chemistry Lab, Fudan University
  • Received:1982-04-12 Online:1984-09-30 Published:1984-09-30

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摘要： 从CF2HCl裂解制备C2F4已有很久历史.七十年代以来不少作者从热分解[1]、分子束技术[2]、以及多光子解离[3~7]等方面对反应机理作了详尽的研究.本文利用连续CO2激光为热源,研究了CF2HCl的非均相反应机理.

Abstract: The pyrolysis of CF2HCl hag been studied. This reaction is a heterogeneous reaction. The reaction channels are depending on the property of surfaces. On Ag surface, the products of this reaction is quite simple, mainly C2F4. The yield of C2F4 is rather high in above reaction. On SiO2 surface, the main by-product is SiF4.