离子型遥爪聚合物分子参数的控制

应用科学学报 ›› 1988, Vol. 6 ›› Issue (1): 6-11.

离子型遥爪聚合物分子参数的控制

颜德岳¹, 王公善², 唐伟枫³

1. 上海交通大学;
2. 同济大学;
3. 华东化工学院

收稿日期:1985-03-21 修回日期:1986-04-22 出版日期:1988-03-31 发布日期:1988-03-31

REGULATION AND CONTROL OF MOLECULAR PARAMETERS OF TELECHELIC POLYMERS

YAN DEYUE¹, WANG GONGSHAN², TANG WEIFONG³

1. Shanghai Jiaotong University;
2. Tongji University;
3. East China Institute of Chemical Technology

Received:1985-03-21 Revised:1986-04-22 Online:1988-03-31 Published:1988-03-31

摘要/Abstract

摘要： 丁基锂和二异丙烯基苯的加成物为引发剂的双官能团活性聚合反应是合成遥爪聚合物的主要途径.本文基于离子型聚合反应的非稳态动力学理论,建立了由反应的初始条件和单体转化率计算这类遥爪聚合物的分子量分布和其他分子参数的方法,并举例进行数值计算,给出了各种分子参数随单体转化率变化的规律.

Abstract: Telechelic polymers are synthesized via bi-functional living polymerization Initiated mainly by the adduct of sec-butyl lithium and m-diisopropenylbenzene. On the basis of the nonsteady state theory of kinetics of anionic polymerization, a method is established, with which the molecular weight distribution and other molecular parameters of the resultant polymer can be calculated from the reaction condition. Several examples of numerical computation are given, the data tabulated and the curves drawn illustrat the relationship between the molecular parameters and monomer conversion.

颜德岳, 王公善, 唐伟枫. 离子型遥爪聚合物分子参数的控制[J]. 应用科学学报, 1988, 6(1): 6-11.

YAN DEYUE, WANG GONGSHAN, TANG WEIFONG. REGULATION AND CONTROL OF MOLECULAR PARAMETERS OF TELECHELIC POLYMERS[J]. Journal of Applied Sciences, 1988, 6(1): 6-11.