交联剂对聚氯乙烯(PVC)电线电缆料辐照交联的影响

应用科学学报 ›› 1989, Vol. 7 ›› Issue (3): 236-242.

交联剂对聚氯乙烯(PVC)电线电缆料辐照交联的影响

王铭钧, 殷明, 常云志, 赵明丽, 章世杰, 张和康

上海交通大学

收稿日期:1987-03-09 修回日期:1988-04-20 出版日期:1989-09-30 发布日期:1989-09-30

THE EFFECT OF SENSITIZERS ON IRRADIATION CROSSLINKING OF POLYVINYL CHLORIDE (PVC)USED AS WIRE AND CABLE

WANG MINGJUN, YIN MING, CHANG YUNZHI, ZHAO MINGLI, ZHANG SHIJIE, ZHANG HEKANG

Shanghai Jiao Tong University

Received:1987-03-09 Revised:1988-04-20 Online:1989-09-30 Published:1989-09-30

摘要/Abstract

摘要： 本文研究了不同交联剂对PVC辐照交联的影响.交联剂的种类及其在PVC中添加的量都会影响XLPVC的热稳定性,各种机械性能和电性能.实验结果表明TMPTMA是一个比较理想的交联剂.本文还讨论了不同交联剂对溶胶分数和剂量关系的影响,并指出InS和交联剂在PVC中添加的量成正比.

Abstract: Generally, pure PVC can not be irradiation crosslinked by electron beams or α-rays; crosslinking agents (or sensitizers) must be used in the irradiation crosslinking of PVC. The effect of the different sensitizers on irradiation crosslinking of PVC has been investigated. The kind of sensitizer and its content in PVC influence the thermal stability, mechanical properties and electrical properties of XLPVC. Experimental results show that TMPTMA is a better sensitizer for irradiation crosslinking of PVC. Also, the effect of different sensitizers on the relationship.between the sol fraction (S) and dose (R) is discussed. It is found that the logarithmic value of sol fraction (InS) is proportional to the sensitizer content in PVC.

王铭钧, 殷明, 常云志, 赵明丽, 章世杰, 张和康. 交联剂对聚氯乙烯(PVC)电线电缆料辐照交联的影响[J]. 应用科学学报, 1989, 7(3): 236-242.

WANG MINGJUN, YIN MING, CHANG YUNZHI, ZHAO MINGLI, ZHANG SHIJIE, ZHANG HEKANG. THE EFFECT OF SENSITIZERS ON IRRADIATION CROSSLINKING OF POLYVINYL CHLORIDE (PVC)USED AS WIRE AND CABLE[J]. Journal of Applied Sciences, 1989, 7(3): 236-242.