含硅醌胺聚合物合成、结构与性能

应用科学学报 ›› 1998, Vol. 16 ›› Issue (2): 243-248.

含硅醌胺聚合物合成、结构与性能

高南, 陆雪芳, 陆成

上海大学

收稿日期:1997-04-25 修回日期:1997-07-21 出版日期:1998-06-30 发布日期:1998-06-30
作者简介:高南:教授,上海大学化学与化学工程学院化学系,上海 201800
基金资助:
国家自然科学基金

Synthesis, Structure and Properties of Slicon Containing Quinone-Amine Polymers

GAO NAN, LU XUEFANG, LU CHENG

Department of Chemistry, Shanghai University, Jiading, Shanghai 201800

Received:1997-04-25 Revised:1997-07-21 Online:1998-06-30 Published:1998-06-30

摘要/Abstract

摘要： 由T,k二氨基烷氧基聚硅氧烷及T,k二氨基烷基聚硅氧烷与对苯醌反应,合成了两类溶解性良好的新型含硅醌胺聚合物,它们与氯磺化聚乙烯、环氧树脂共混固化后获得吸水率低,抗盐水性优良的防水、防锈涂膜.

关键词: 有机硅二胺, 氯磺化聚乙烯, 环氧树脂, 醌胺聚合物

Abstract: Two new kinds of soluble silicon containing quinone amine polymers (PQA) were synthesized by T,k-diaminoalkoxy polymethylsiloxane and T,k-diaminoalkyl polymethylsiloxane reacted with p-benzoquinone. PQA can be cured by mixing chloro sulphonated polyethylene and epoxy resin, and the products are a kind of water-proof and rust-proof coating film with low moisture absorption and good saltwater resistance.

Key words: silicone diamines, quinone amine polymers, chloro-sulphonated polyethy-lene, water-proof coating, epoxy resin

高南, 陆雪芳, 陆成. 含硅醌胺聚合物合成、结构与性能[J]. 应用科学学报, 1998, 16(2): 243-248.

GAO NAN, LU XUEFANG, LU CHENG. Synthesis, Structure and Properties of Slicon Containing Quinone-Amine Polymers[J]. Journal of Applied Sciences, 1998, 16(2): 243-248.